An {Fe60} tetrahedral cage: building nanoscopic molecular assemblies through cyanometallate and alkoxo linkers.

نویسندگان

  • J-R Jiménez
  • A Mondal
  • L-M Chamoreau
  • P Fertey
  • F Tuna
  • M Julve
  • A Bousseksou
  • R Lescouëzec
  • L Lisnard
چکیده

A nanoscopic {Fe60} coordination cage (approximately 3 nm) was prepared by the self assembly of a partially blocked tricyanidoferrate(iii) complex and tris(alkoxo)-based iron(iii) coordination motifs. This cage is a rare example of a mixed cyanido/alkoxo-bridged high nuclearity complex and it exemplifies the great potential of this new synthetic route to generate uncommon molecular architectures using cyanometallates as metalloligands versus alkoxo-based polynuclear entities.

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عنوان ژورنال:
  • Dalton transactions

دوره 45 44  شماره 

صفحات  -

تاریخ انتشار 2016